Finfet with multilayer fins for multi-value logic (mvl) applications and method of forming

ABSTRACT

A method of forming a multi-valued logic transistor with a small footprint and the resulting device are disclosed. Embodiments include forming plural fins on a silicon substrate, each fin covered with a hardmask; filling spaces between the fins and hard masks with an oxide; removing the hardmasks and recessing each fin, forming a cavity in the oxide over each fin; forming plural Si-based layers in each cavity with an increasing percentage of Ge or C or with an decreasing concentration of dopant from a bottom layer to a top layer; performing CMP for planarization to a top of the fins; recessing the oxide to a depth slightly below a top portion of the fin having a thickness equal to a thickness of each Si-based layer; and forming a high-k gate dielectric and a metal gate electrode over the plural Si-based layers.

RELATED APPLICATION

The present application is a Divisional application of application Ser.No. No. 14/175,827, filed on Feb. 7, 2014, which is incorporated hereinby reference in its entirety.

TECHNICAL FIELD

The present disclosure relates to multi-valued logic (MVL) transistors.The present disclosure is particularly applicable to 14 nanometer(nm)—extreme mobility (14 XM) and 10 nm FinFET technology nodes andbeyond.

BACKGROUND

Conventional structures of transistors which can process multiple logicstates are typically formed, as illustrated in FIGS. 1A and 1B, bytransistors with multiple threshold voltages (e.g., V_(t0), V_(t1), andV_(t2)) and a shared common gate electrode 101. Therefore, an N-statetransistor is practically composed of N transistors sharing a commongate (i.e., having a footprint of N transistors). As illustrated in FIG.1C, the structure of FIGS. 1A and 1B processes four levels of logicsignal (or 2 bits), 00, 01, 10, and 11, with the 2-bits of informationat input V_(g) represented by the 2-bits information in the outputcurrent (I_(d)). The footprint of each 2 bit logic transistor isactually three times that of a single binary logic transistor, thoughmulti-value logic is much more efficient and faster than current binarylogic. Furthermore, the fabrication method to form multi-V_(t) for eachtransistor is complicated and costly.

A need therefore exists for methodology enabling formation ofmulti-value logic transistor structures with a small footprint and theresulting device.

SUMMARY

An aspect of the present disclosure is a multi-valued logic transistorwith a footprint of a single fin.

Another aspect of the present disclosure is a method of forming amulti-valued logic transistor with a footprint of a single fin.

Additional aspects and other features of the present disclosure will beset forth in the description which follows and in part will be apparentto those having ordinary skill in the art upon examination of thefollowing or may be learned from the practice of the present disclosure.The advantages of the present disclosure may be realized and obtained asparticularly pointed out in the appended claims.

According to the present disclosure, some technical effects may beachieved in part by a method including: forming plural fins on a siliconsubstrate, each fin covered with a hardmask; filling spaces between thefins and hardmasks with an oxide; removing the hardmasks and recessingeach fin, forming a cavity in the oxide over each fin; forming pluralsilicon-based (Si-based) layers in each cavity with an increasingpercentage of germanium (Ge) or carbon (C) content or with an increasingconcentration of dopant from a bottom layer to a top layer; recessingthe oxide to a depth slightly (about 5 nm) below a top portion of thefin having a thickness equal to a thickness of each Si-based layer; andforming a high-k gate dielectric and metal gate electrode over theplural Si-based layers.

Aspects of the present disclosure include recessing the fins removingthe hardmask from the fins with hot phosphorus and recessing the fins byplasma Si etching. A further aspect includes forming each cavity to adepth of 40 nanometers (nm), wherein each cavity has an aspect ratio of5:1 or less. An additional aspect includes forming each Si-based layerto a thickness of 10 to 15 nm. Another aspect includes forming theSi-based layers sequentially by epitaxial growth. Other aspects includeforming the layers by selective epi growth (SEG) of silicon germanium(SiGe) with an increasing percentage of Ge. Further aspects include thepercentage of Ge ranging from 0 to 50%. Another aspect includes formingthe Si-based layers by SEG of carbon-doped silicon (Si:C) with anincreasing percentage of C. Other aspects include the percentage of Cranging from 0 to 2%. An additional aspect includes forming the Si-basedlayers by SEG with in situ doping an increasing concentration of dopant(e.g., boron (B) for p-type and phosphorus (P) or arsenic (As) forn-type dopants). A further aspect includes the concentration of dopantranging from 1E18 to 1E20.

Another aspect of the present disclosure is a device including: pluralfins on a silicon substrate; an oxide filling spaces between the fins;each fin having plural Si-based layers stacked up with an increasingpercentage of Ge or C and/or with an decreasing concentration of dopantfrom a bottom layer to a top layer; and a high-k dielectric and metalgate electrode over the plural Si-based layers, with a Vt of each layerprogressively decreasing from the bottom layer. Thus, there are multipleVt's built in each FinFET.

Aspects of the present disclosure include each Si-based layer having athickness of 10 to 15 nm. Further aspects include the layers includingselective epi growth (SEG) SiGe with an increasing percentage of Ge.Other aspects include the percentage of Ge ranging from 0 to 50%.Another aspect includes the layers including SEG Si:C with an increasingpercentage of C. An additional aspect includes the percentage of Cranging from 0 to 2%. A further aspect includes the layers including SEGin situ doped Si with a decreasing concentration of dopant. Otheraspects include the concentration of dopant ranging from 1E18 to 1E20.

Another aspect of the present disclosure is a method including: formingplural fins on a silicon substrate, each fin covered with a hardmask;filling spaces between the fins and hardmasks with an oxide; planarizingthe oxide; removing the hardmasks and recessing each fin with hotphosphorus, forming a cavity to a depth of 40 nm in the oxide over eachfin; masking cavities over fins for p-FinFETs, exposing fins forn-FinFETS; epitaxially growing plural Si-based layers in each cavitywith a percentage of C increasing between 0 and 2% or with aconcentration of p-type dopant decreasing between 1E18 and 1E20 from abottom layer to a top layer; masking cavities over fins for n-FinFETs,exposing fins for p-FinFETS; epitaxially growing plural Si-based layersin each cavity with a percentage of Ge increasing between 0 and 50% orwith a concentration of n-type dopant decreasing between 1E18 and 1E20from a bottom layer to a top layer; performing CMP for planarization toa top of the fins; recessing the oxide to a depth slightly (about 5 nm)below a top portion of the fins having a thickness equal to a thicknessof each Si-based layer, and forming a high-k dielectric and metal gateelectrode over the plural Si-based layers and wrapped around the fins.

Additional aspects and technical effects of the present disclosure willbecome readily apparent to those skilled in the art from the followingdetailed description wherein embodiments of the present disclosure aredescribed simply by way of illustration of the best mode contemplated tocarry out the present disclosure. As will be realized, the presentdisclosure is capable of other and different embodiments, and itsseveral details are capable of modifications in various obviousrespects, all without departing from the present disclosure.Accordingly, the drawings and description are to be regarded asillustrative in nature, and not as restrictive.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is illustrated by way of example, and not by wayof limitation, in the figures of the accompanying drawing and in whichlike reference numerals refer to similar elements and in which:

FIGS. 1A and 1B schematically illustrate a conventional multi-valuelogic transistor structure, and FIG. 1C shows the output current foreach V_(t) value;

FIGS. 2A and 2B schematically illustrate cross-sectional and3-dimensional views, respectively, of a multi-valued logic transistor,in accordance with an exemplary embodiment;

FIG. 3A schematically illustrates energy-band levels in Si, SiGe, and Geand FIG. 3B schematically illustrates energy-band levels in Si, Si—Ge—C,and Si:C;

FIGS. 4A through 4F schematically illustrate a process flow for forminga multi-valued logic transistor, in accordance with an exemplaryembodiment.

DETAILED DESCRIPTION

In the following description, for the purposes of explanation, numerousspecific details are set forth in order to provide a thoroughunderstanding of exemplary embodiments. It should be apparent, however,that exemplary embodiments may be practiced without these specificdetails or with an equivalent arrangement. In other instances,well-known structures and devices are shown in block diagram form inorder to avoid unnecessarily obscuring exemplary embodiments. Inaddition, unless otherwise indicated, all numbers expressing quantities,ratios, and numerical properties of ingredients, reaction conditions,and so forth used in the specification and claims are to be understoodas being modified in all instances by the term “about.”

The present disclosure addresses and solves the current problem of alarge footprint attendant upon forming a multi-valued logic transistor.In accordance with embodiments of the present disclosure, multiplethreshold voltages (Vt) are obtained by forming multi-layered fins withan increasing percentage of Ge or C and/or an decreasing concentrationof dopant from a bottom layer to a top layer, so that the Vt of each finlayer decreases progressively from the bottom layer to the top layer anda multi-valued Vt is therefore built-in for a FinFET even with onesingle fin.

Methodology in accordance with embodiments of the present disclosureincludes forming plural fins on a silicon substrate, each fin coveredwith a hardmask, and filling the spaces between the fins and hard maskswith an oxide. Next, the hardmasks (typically nitride) are removed(e.g., by hot phosphorous acid), and the fins are recessed, forming acavity in the oxide over each fin. Plural Si-based layers are thenformed in each cavity with an increasing percentage of Ge or C or withan decreasing concentration of dopant from a bottom layer to a toplayer, so that the Vt of each layer decrease progressively from bottomlayer. After CMP for planarization, the oxide is next recessed to adepth slightly lower than a top portion of the fin having a thicknessequal to a thickness of each Si-based layer, and a high-k dielectric andmetal gate electrode is formed over the plural Si-based layers.

Still other aspects, features, and technical effects will be readilyapparent to those skilled in this art from the following detaileddescription, wherein preferred embodiments are shown and described,simply by way of illustration of the best mode contemplated. Thedisclosure is capable of other and different embodiments, and itsseveral details are capable of modifications in various obviousrespects. Accordingly, the drawings and description are to be regardedas illustrative in nature, and not as restrictive.

Adverting to FIGS. 2A and 2B, cross-sectional and 3D views,respectively, of a FinFET with a multi-layer fin are illustrated, inaccordance with an exemplary embodiment. As shown, a silicon fin, withbottom portion 201, extends vertically from a silicon substrate 203. Anoxide layer 205 is formed adjacent to and coplanar with fin bottomportion 201. Multiple fin layers 207, 209, and 211 of silicon withincreasing percentages of Ge or C, and/or decreasing concentrations of adopant for the purpose of adjusting the threshold voltage (Vt) of eachlayer, from the bottom layer to the top layer, are formed on fin bottomportion 201. The relationship between the Ge or C percentages, with thevalues being at evenly spaced intervals, minimizes the strain in eachlayer from the substrate 203. Similarly, the dopant concentrations canalso be substantially uniform at evenly spaced intervals. If necessary,the percentage of Ge or C may be reduced again in upper layers. A metalgate electrode 213 is formed over the silicon fin (wrapping-around thefin and extending to a depth slightly (i.e. about 5 nm) below a topportion of the fin having a thickness equal to a thickness of eachSi-based layer), with an intervening high-k gate dielectric layer (notshown for illustrative convenience). Although four fin layers (includingbottom layer 201) are shown in FIGS. 2A and 2B, for two bits, morelayers may be formed for more additional bits. In addition, thepercentage of Ge or C may vary continuously for analog signals.

In FIGS. 2A and 2B, for a P-FinFET, layers 207 through 211 may be formedof SiGe. The SiGe may be SiGe_(0.15), SiGe_(0.30), and SiGe_(0.45),respectively, for layers 207, 209, and 211, for three thresholdvoltages, V_(t0), V_(t1), and V_(t2). The progressively higher Gepercentage in the SiGe channels toward the top results in a valence bandedge being progressively shifted (toward mid-gap); as a result, the Vtof the p-FinFET decreases the amount of band-gap edge shifted,respectively, and Vt is shifted toward a lower magnitude (i.e.V_(t0)>V_(t1)>V_(t2) in magnitudes). The Ge containing Si layer (orSiGe) is preferred for p-FinFET due to its compressive stress in a SiGefilm, resulting in higher hole mobility (than pure Si layer).

Energy-band levels in Si, SiGe, and Ge are shown at 301, 303, and 305,respectively, in FIG. 3A. The band-gap of SiGe is smaller than Si mainlydue to the valence band edge shift (about 10 millivolt (mV) per atomic(at.) percent of Ge) toward the mid-band (but negligible conduction bandshift). Thus, for a p-FinFET design, the multi-layers of SiGe in the fincan maintain non-doping with progressively higher percentages of Getoward the top, so that the valence band edge is progressively shifted(toward mid-gap) and the p-Vt is shifted toward lower magnitudes. As anadded advantage, the p-FinFET has a fully depleted channel (duringoperations) as well as a compressively strained channel with enhancedhole mobility.

In FIGS. 2A and 2B, for an n-FinFET, layers 207 through 211 may beformed of Si:C. The Si:C may be Si, Si:C_(1%), and Si:C_(2%),respectively, for layers 207, 209, and 211, for three thresholdvoltages, V_(t0), V_(t1), and V_(t2). The progressively higher Cpercentage in the Si channels toward the top results in a conductionband edge being progressively shifted (toward mid-gap); as a result, theVt of the p-FinFET (or n-FinFET) decreases the amount of band-gap edgeshifted, respectively, and Vt is shifted toward a lower magnitude (i.e.V_(t0)>V_(t1)>V_(t2) in magnitudes). The C containing layer is preferredfor n-FinFET due to its tensile stress in film and resulting in higherelectron mobility (than pure Si layer).

Energy-band levels in Si, Si—Ge—C, and Si:C are shown at 307, 309, and311, respectively, in FIG. 3B. The C doping in Si mainly results in aconduction band edge shift (about 30 mV per at. percent of C) toward themid-band. Thus, for an n-FinFET design, the multi-layers of Si:C in thefin can maintain non-doping with progressively higher percentages of Ctoward the top, so that the conduction band edge is progressivelyshifted (toward mid-gap) and the n-Vt is shifted toward lowermagnitudes. As an added advantage, the n-FinFET has a fully depletedchannel (during operations) as well as a tensile strained channel withenhanced electron mobility.

Layers 207 through 211 in FIGS. 2A and 2B may alternatively be doped Si,with progressively lower doping concentrations from layer 207 to layer211 for three threshold voltages, V_(t0), V_(t1), and V_(t2),respectively. For an n-FinFET, the layers have a p-type dopant (e.g.,boron (B)), and for a p-FinFET, the layers have an n-type dopant (e.g.,phosphorus (P), arsenic (As), or antimony (Sb)). The lower dopingconcentrations may be in the range of 1E18 to 1E20 to tune the Vtsmaller in magnitude in a useful range of 0.1 to 0.5 volts (V). When thelayers are doped, strain engineering can be provided during a later stepof the FinFET fabrication in which an epi-stressor is grown at thesource/drain regions. The higher doping at the bottom layer has theadvantages of serving as “punch-through” isolation to suppress thepunch-through leakage between the drain and source at minimum gatelength. In this disclosure, the ability of Vt adjustment is achieved byeither or both of the effects of Ge or C content and dopantconcentration. Further, the doping may increase from the bottom layertowards the top layer, or a pattern of Ge or C content or of dopingconcentration may be created and/or repeated for specific purposes, forexample for an analog gate bias or if a non-linear output (draincurrent) is desired.

Adverting to FIGS. 4A through 4F, process steps for forming the FinFETof FIGS. 2A and 2B with a multi-layer fin are illustrated. As shown inFIG. 4A, a silicon substrate 401 is etched to form fins 403. Thesubstrate may be silicon-on-insulator (SOI) or bulk (100) silicon with<110> or <100> direction (a 45° rotation from <110>). The substrate isetched by conventional mandrel and spacer pitch doubling methods. Forexample, a hardmask (not shown for illustrative convenience) may bedeposited on the substrate and patterned to form mandrels. Next, spacersmay be formed on the sides of the mandrels, and the mandrels may beremoved. The spacers, which may be formed of silicon nitride (Si₃N₄),may then be used as a hardmask 405 for etching the silicon substrate toform the fins. The fins may be formed to a height 407 of less than 40nm, and the spacers forming mask 405 may have a height 409 of about 30nm. The width 411 of the fins may be about 7 nm, and the pitch 413 ofthe fins may be 28 to 40 nm.

As illustrated in FIG. 4B, the trenches formed between fins 403 andhardmask 405 are filled with an oxide 415. The oxide may be, forexample, silicon oxide (SiO₂). Oxide 515 is then planarized, for exampleby chemical mechanical polishing (CMP), stopping on the hardmask 405.

Next, hardmask 405 is removed by hot phosphorus, and the fins arerecessed, forming cavities 417, as illustrated in FIG. 4C. The cavitiesare recessed to a depth of about 40 nm and have a width of 7 nm. Inother words, the cavities are formed to have an aspect ratio of about5:1 for manufacturability.

Adverting to FIG. 4D, multiple layers 419, 421, and 423 are selectivelyepitaxially grown in cavities 417. Each layer may be formed to athickness of 10 to 15 nm and a width of 7 nm. Although three layers areshown (for a 2 bit device), more layers may be included for more bits,for which the layers may then be formed to a thickness of 5 to 10 nm.Process parameters during the epitaxial growth of gas flow, pressure,temperature, can be tuned for high quality Si-based film formation withminimum defects. For example, the gas flow may include silane (SiH₄),dichlorosilane (Si₂Cl₂), or hydrogen (H₂), pressure may range from 1 to200 Torr, and the temperature may range from 300° to 1000° C. Fins forn-type and p-type FinFETs may be separately optimized by adding extramasking steps (not shown for illustrative convenience) for epitaxialgrowth only on exposed areas of Si.

For a p-FinFET, layers 419, 421, and 423 may be formed of epitaxiallygrown SiGe. The SiGe may be SiGe_(0.15), SiGe_(0.30), and SiGe_(0.45),respectively, for layers 419, 421, and 423, for three thresholdvoltages, V_(t0), V_(t1), and V_(t2). For an n-FinFET, layers 419, 421,and 423 may be formed of epitaxially grown Si:C. The Si:C may be Si,Si:Cm, and Si:C_(2%), respectively, for layers 419, 421, and 423, forthree threshold voltages, V_(t0), V_(t1), and V_(t2). The percentages ofGe or C may alternatively vary continuously from the bottom layer to thetop layer to handle analog signals.

Layers 419, 421, and 423 may alternatively be doped Si, withprogressively lower doping concentrations from layer 419, 421, and 423for three threshold voltages, V_(t0), V_(t1), and V_(t2), respectively.For an n-FinFET, the layers have a p-type dopant (e.g., B), and for ap-FinFET, the layers have an n-type dopant (e.g., P, As, or Sb). Thedoping concentrations are in the range of 1E18 to 1E20, so that Vt istuned in a useful range of 0.1 to 0.5 V. Further, the epitaxial growthfor Si, SiGe, Si:C, and in situ doping can all be performed in onechamber. Note the Vt adjustment can be achieved by either or bothadjustment of Ge or C content as well as the dopant concentration. Also,a Vt adjustment may be achieved by progressively increasing the dopantconcentration from the bottom layer to the top layer, or a pattern of Geor C content or of doping concentration may be created and/or repeatedfor specific purposes, for example for an analog gate bias or if anon-linear output (drain current) is desired.

After the layers 419, 421, and 423 are formed, they are planarized byCMP, and oxide 415 is recessed down to a depth slightly below (i.e. 5 nmbelow) the bottom of portion 403 a of fin 403 (portion 403 a having thesame thickness as each of layers 419, 421, and 423), as illustrated inFIG. 4E. A conventional plasma dry etch may be employed to recess theoxide, with the depth controlled by a timed etch. Adverting to FIG. 4F,a high-k dielectric (not shown for illustrative convenience) and gateelectrode may then be formed over and wrapped-around the layers 419,421, 423, and 403 for each fin.

The embodiments of the present disclosure can achieve several technicaleffects, such as multi-valued logic transistors with a small footprintof a single fin, the thickness and percentage of Ge or C and/or theconcentration of dopant can be progressively varied to set the multiplelayers, n-type and p-type fins can be separately optimized by epitaxialgrowth of different materials and stress levels for high performance andlow leakage, and FinFETs for multi-valued logic and binary logic can beformed together on the same chip. The present disclosure enjoysindustrial applicability in any of highly integrated MVL semiconductordevices, including an analog device, a decoder of analog signals, or asensor of analog non-volatile memory.

In the preceding description, the present disclosure is described withreference to specifically exemplary embodiments thereof. It will,however, be evident that various modifications and changes may be madethereto without departing from the broader spirit and scope of thepresent disclosure, as set forth in the claims. The specification anddrawings are, accordingly, to be regarded as illustrative and not asrestrictive. It is understood that the present disclosure is capable ofusing various other combinations and embodiments and is capable of anychanges or modifications within the scope of the inventive concept asexpressed herein.

What is claimed is:
 1. A device comprising: plural fins on a siliconsubstrate; an oxide filling spaces between the fins; each fin havingplural silicon-based (Si-based) layers stacked up with an increasingpercentage of germanium (Ge) or carbon (C) and/or with a decreasingconcentration of dopant from a bottom layer to a top layer; and a metalgate electrode over the plural Si-based layers, with a Vt of each layerprogressively decreasing from the bottom layer.
 2. The device accordingto claim 1, wherein each Si-based layer has a thickness of 10 to 15 nm.3. The device according to claim 1, wherein the Si-based layers compriseepi growth (SEG) silicon germanium (SiGe) with an increasing percentageof Ge.
 4. The device according to claim 3, wherein the percentage of Geranges from 0 to 50%.
 5. The device according to claim 1, wherein theSi-based layers comprise SEG carbon-doped silicon (Si:C) with anincreasing percentage of C.
 6. The device according to claim 5, whereinthe percentage of C ranges from 0 to 2%.
 7. The device according toclaim 1, wherein the Si-based layers comprise SEG in situ doped silicon(Si) with an increasing concentration of dopant.
 8. The device accordingto claim 7, wherein the concentration of dopant ranges from 1E18 to1E20.
 9. The device according to claim 1, wherein the oxide has athickness of 10 to 15 nm.
 10. The device according to claim 1, whereinthe silicon substrate comprises silicon-on-insulator (SOI) or bulk (100)silicon.
 11. A device comprising: fins formed on a silicon substrate; anoxide filling spaces between the fins; silicon-based (Si-based) layersformed in each cavity with an increasing percentage of germanium (Ge) orcarbon (C) content or with an increasing concentration of dopant from abottom layer to a top layer; a gate electrode formed over the Si-basedlayers.
 12. The device according to claim 11, wherein each Si-basedlayer has a thickness of 10 to 15 nm.
 13. The device according to claim11, wherein the Si-based layers comprise epi growth (SEG) silicongermanium (SiGe) with an increasing percentage of Ge.
 14. The deviceaccording to claim 13, wherein the percentage of Ge ranges from 0 to50%.
 15. The device according to claim 11, wherein the Si-based layerscomprise SEG carbon-doped silicon (Si:C) with an increasing percentageof C.
 16. The device according to claim 15, wherein the percentage of Cranges from 0 to 2%.
 17. The device according to claim 11, wherein theSi-based layers comprise SEG in situ doped silicon (Si) with anincreasing concentration of dopant.
 18. The device according to claim17, wherein the concentration of dopant ranges from 1E18 to 1E20.
 19. Adevice comprising: n-FINFETs fins and p-FINFETs fins formed on a siliconsubstrate; an oxide filling spaces between the n-FINFETs fins andp-FINFETs fins; each n-FINFET fin having silicon-based (Si-based) layersstacked up with a percentage of carbon (C) increasing between 0 and 2%or with a concentration of p-type dopant decreasing between 1E18 and1E20 from a bottom layer to a top layer; each p-FINFET fin havingsilicon-based (Si-based) layers stacked up with a percentage ofgermanium (Ge) increasing between 0 and 50% or with a concentration ofn-type dopant decreasing between 1E18 and 1E20 from a bottom layer to atop layer; and a high-k gate dielectric and metal gate electrode overthe plural Si-based layers and wrapped around the fins.
 20. The deviceaccording to claim 19, wherein a Vt of each layer progressivelydecreases from the bottom layer.